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Species: Rhodobacter sphaeroides

Methylselanylmethane

Compound Details

Synonymous names
Dimethylselenide
DIMETHYL SELENIDE
593-79-3
Dimethylselenium
Methyl selenide
Methyl selenium
Methane, selenobis-
(Methylselanyl)methane
methylselanylmethane
Selenide, dimethyl-
Selenium dimethyl
(CH3)2Se
YK0R6JKT6H
EINECS 209-807-4
UNII-YK0R6JKT6H
BRN 1696848
dimethylselane
Selenobismethane
Dimethyl-Selenide
HSDB 7900
Selenobis-Methane
MFCD00014848
Selenobismethane, 9CI
Methyl selenide, 8CI
Methyl selenide (8CI)
(Methylselanyl)methane #
Methane, selenobis- (9CI)
4-01-00-01288 (Beilstein Handbook Reference)
DIMETHYLSELENIDE [HSDB]
CHEBI:4610
DTXSID6074752
AKOS015840123
Dimethyl selenide, >=99.0% (GC)
HY-W174486
CS-0235614
D1289
NS00080219
C02535
T71107
EN300-1590162
Q22668715
Microorganism:

Yes

IUPAC namemethylselanylmethane
SMILESC[Se]C
InchiInChI=1S/C2H6Se/c1-3-2/h1-2H3
FormulaC2H6Se
PubChem ID11648
Molweight109.04
LogP0
Atoms3
Bonds0
H-bond Acceptor0
H-bond Donor0
Chemical Classificationselenides
CHEBI-ID4610
Supernatural-IDSN0336279

mVOC Specific Details

Boiling Point
DegreeReference
57 deg CLide, D.R. CRC Handbook of Chemistry and Physics 88TH Edition 2007-2008. CRC Press, Taylor & Francis, Boca Raton, FL 2007, p. 3-210
Volatilization
Selenium volatilizes from soils at rates that are modified by temperature, moisture, time, season or year, concentration of water soluble selenium, and microbiological activity. Conversion of inorganic and organic selenium compounds to volatile selenium compounds (such as dimethyl selenide, dimethyl diselenide, and an unknown compound) by microorganisms has been observed in lake sediments of the Sudbury area of Ontario. This conversion may have been effected by pure cultures of Aeromonas, Flavobacterium, Pseudomonas, or an unidentified fungus, all of which are found in methylated lake sediments. Production of volatile selenium is temperature dependent. Compared with the amount of dimethyl Se produced at an incubation temperature of 20 deg C, 25% less was produced at 10 deg C and 90% less at 4 deg C.
Literature: Eisler R; Selenium hazards to fish, wildlife and invertebrates: a synoptic review. U.S. Fish and Wildlife Service Biological Report 85 (1.5) p.4 (1985)
Soil Adsorption
The Kd values measured in unamended, manure-amended and gluten-amended Hanford sandy loam at 4 deg C were 0.038, 0.091 and 0.045, respectively; there was no detection at temperatures of 21 and 40 deg C, or in Losthill clay loam under the same conditions(1).
Literature: (1) Guo L et al; Environ Sci Technol 33: 2934-8 (1999)
Vapor Pressure
PressureReference
32 kPaZhang YQ et al; Environ Sci Technol 33: 3415-20 (1999)
MS-Links

Species emitting the compound
KingdomSpeciesBiological FunctionOrigin/HabitatReference
ProkaryotaRhodocyclus Tenuisn/aNASchulz and Dickschat 2007
ProkaryotaRhodospirillum Rubrumn/aNASchulz and Dickschat 2007
ProkaryotaRhodobacter Sphaeroidesn/aNASchulz and Dickschat 2007
ProkaryotaEnterobacter Cloacaen/aNASchulz and Dickschat 2007
ProkaryotaAeromonas Veroniin/aNASchulz and Dickschat 2007
ProkaryotaGeobacillus Stearothermophilusn/aNASchulz and Dickschat 2007
EukaryotaPenicillium Sp.n/aNAStotzky and Schenck 1976
EukaryotaAspergillus Sp.n/aNAStotzky and Schenck 1976
EukaryotaScopulariopsis Brevicaulisn/aNAStotzky and Schenck 1976
EukaryotaCandida Humicolan/aNAStotzky and Schenck 1976
EukaryotaSchizophyllum Communen/aNAStotzky and Schenck 1976
ProkaryotaMethanobacterium Formicicumn/aNAMichalke et al. 2000
ProkaryotaMethanosarcina Barkerin/aNAMichalke et al. 2000
ProkaryotaClostridium Collagenovoransn/aNAMichalke et al. 2000
ProkaryotaDesulfovibrio Vulgarisn/aNAMichalke et al. 2000
ProkaryotaDesulfovibrio Gigasn/aNAMichalke et al. 2000
Method
KingdomSpeciesGrowth MediumApplied MethodVerification
ProkaryotaRhodocyclus Tenuisn/an/ano
ProkaryotaRhodospirillum Rubrumn/an/ano
ProkaryotaRhodobacter Sphaeroidesn/an/ano
ProkaryotaEnterobacter Cloacaen/an/ano
ProkaryotaAeromonas Veroniin/an/ano
ProkaryotaGeobacillus Stearothermophilusn/an/ano
EukaryotaPenicillium Sp.n/an/ano
EukaryotaAspergillus Sp.n/an/ano
EukaryotaScopulariopsis Brevicaulisn/an/ano
EukaryotaCandida Humicolan/an/ano
EukaryotaSchizophyllum Communen/an/ano
ProkaryotaMethanobacterium Formicicumn/an/ano
ProkaryotaMethanosarcina Barkerin/an/ano
ProkaryotaClostridium Collagenovoransn/an/ano
ProkaryotaDesulfovibrio Vulgarisn/an/ano
ProkaryotaDesulfovibrio Gigasn/an/ano