Results for:
PubChem ID: 14896

6,6-dimethyl-4-methylidenebicyclo[3.1.1]heptane

Mass-Spectra

Compound Details

Synonymous names
Pseudopinene
Terebenthene
Pseudopinen
Terbenthene
Nopinene
Rosemarel
WTARULDDTDQWMU-UHFFFAOYSA-N
Nopinen
beta-Pinene homopolymer
beta pinene
BETA-PINENE
ss-Pinene
AC1Q2AIT
B-pinene
beta-Pinene resin
PINENE, BETA
AC1L24RF
I943
Piccolyte 115
.beta.-Pinene
beta-Pinene (natural)
P0441
6,6-Dimethyl-2-methylenenorpinane
CHEMBL501351
laevo-.beta.-Pinene
NSC21447
NSC59190
Beta Pinene 95 PF
Beta Pinene PF 85%
Beta Pinene PF 95%
Beta Pinene T 85%
Beta Pinene T 95%
C09882
HSDB 5615
AK113983
BT000141
DTXSID7027049
Jsp001748
L-.beta.-Pinene
LS-3052
NSC406265
OR025387
OR211823
OR213994
SBB061306
CHEBI:50025
DSSTox_CID_7049
( inverted exclamation markA)-b-pinene
6,6-dimethyl-2-methylene-norpinane
AB1006761
AN-18767
AN-23009
DSSTox_GSID_27049
EBD2156726
NSC 21447
NSC-21447
NSC-59190
SC-48739
D-alpha-PINENE, 95%
DSSTox_RID_78293
2(10)-Pinene
AI3-24483
NSC-406265
ST50330587
AKOS004119987
(-)-b-Pinene
4CH-024531
FEMA No. 2903
FT-0604382
FT-0622936
I14-45220
Pin-2(10)-ene
Tox21_200029
127-91-3
9081-94-1
NCGC00248498-01
NCGC00257583-01
(-)-.beta.-Pinene
CAS-127-91-3
EINECS 204-872-5
EINECS 245-424-9
25719-60-2
37203-45-5
39475-62-2
50922-56-0
51273-99-5
55963-81-0
55963-82-1
59828-47-6
59828-48-7
60976-31-0
211108-08-6
(+)-I(2)-Pinene
MolPort-004-956-468
6,6-dimethyl-2-methylidenebicyclo[3.1.1]heptane
6,6-dimethyl-4-methylidenebicyclo[3.1.1]heptane
6,6-Dimethyl-2-methylenebicyclo(3.1.1)heptane
6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane
(1S)-(-)-b-Pinene
(-)-2(10)-Pinene
Bicyclo[3.1.1]heptane,6-dimethyl-2-methylene-
2,6-Trimethylbicyclo[3.1.1]hept-2-ene
6,6-Dimethyl-2-methylene-bicyclo(3.1.1)heptane
(-)-Pin-2(10)-ene
.beta.-Pinene-(1S)-(-)
(1S)-(-)-.beta.-Pinene
(1S,5S)-2-(10)-Pinene
2,2,6-Trimethylbicyclo(3.1.1)hept-2-ene
Bicyclo(3.1.1)heptane, 6,6-dimethyl-2-methylene-
Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-
(1)-6,6-Dimethyl-2-methylenebicyclo(3.1.1)heptane
BICYCLO(3.1.1)HEPTANE, 6,6-DIMETHYL-2-METHYLENE-, HOMOPOLYMER
(1S,5S)-6,6-Dimethyl-2-methylenebicyclo[3.1.1] heptane
6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane-, (S)-
2(10)-Pinene, (1S,5S)-(-)-
Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-, (1S)-
Bicyclo(3.1.1)heptane, 6,6-dimethyl-2-methylene-, (1S,5S)-
Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-, (1S,5S)-
2(10)-Pinene; 6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane; Pin-2(10)-ene
Microorganism:

Yes

IUPAC name6,6-dimethyl-4-methylidenebicyclo[3.1.1]heptane
SMILESCC1(C2CCC(=C)C1C2)C
InchiInChI=1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h8-9H,1,4-6H2,2-3H3
FormulaC10H16
PubChem ID14896
Molweight136.238
LogP2.86
Atoms26
Bonds27
H-bond Acceptor0
H-bond Donor0
Chemical ClassificationTerpenes Ketones Bicyclo Alkane

mVOC Specific Details

Boiling Point
DegreeReference
166 deg CLide, D.R. CRC Handbook of Chemistry and Physics 86TH Edition 2005-2006. CRC Press, Taylor & Francis, Boca Raton, FL 2005, p. 3-436
Volatilization
The Henry's Law constant for beta-pinene is estimated as 0.16 atm-cu m/mole(SRC) using a fragment constant estimation method(1). This Henry's Law constant indicates that beta-pinene is expected to volatilize rapidly from water surfaces(2). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(2) is estimated as 3 hours(SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(2) is estimated as 5 days(SRC). beta-Pinene's Henry's Law constant indicates that volatilization from moist soil surfaces may occur(SRC). However, volatilization from water surfaces is expected to be attenuated by adsorption to suspended solids and sediment in the water column. The volatilization half-life from a model pond is about 340 days when adsorption is considered(3). beta-Pinene is expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 2.93 mm Hg(4).
Literature: (1) Meylan WM, Howard PH; Environ Toxicol Chem 10: 1283-93 (1991) (2) Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 15-1 to 15-29 (1990) (3) US EPA; EXAMS II Computer Simulation (1987) (4) Daubert TE, Danner RP; Physical and Thermodynamic Properties of Pure Chemicals Data Compilation. Washington, DC: Taylor and Francis (1989)
Solubility
ALMOST INSOL IN PROPYLENE GLYCOL
Literature: Fenaroli's Handbook of Flavor Ingredients. Volume 2. Edited, translated, and revised by T.E. Furia and N. Bellanca. 2nd ed. Cleveland: The Chemical Rubber Co., 1975., p. 486
Literature: #Soluble in benzene, ethanol and ethyl ether
Literature: Lide, D.R. CRC Handbook of Chemistry and Physics 86TH Edition 2005-2006. CRC Press, Taylor & Francis, Boca Raton, FL 2005, p. 3-436
Literature: #Soluble in alcohol and chloroform
Literature: O'Neil, M.J. (ed.). The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. Whitehouse Station, NJ: Merck and Co., Inc., 2006., p. 1283
Literature: #In water, 4.89 mg/L at 25 deg C (est)
Literature: US EPA; Estimation Program Interface (EPI) Suite. Ver.3.12. Nov 30, 2004. Available from, as of Sept 24, 2008: http://www.epa.gov/oppt/exposure/pubs/episuitedl.htm
Soil Adsorption
The Koc of beta-pinene is estimated as 4,400(SRC), using a log Kow of 4.16(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that beta-pinene is expected to have slight mobility in soil.
Literature: The Koc of beta-pinene is estimated as 4,400(SRC), using a log Kow of 4.16(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that beta-pinene is expected to have slight mobility in soil.
Vapor Pressure
PressureReference
2.93 mm Hg at 25 deg CDaubert, T.E., R.P. Danner. Physical and Thermodynamic Properties of Pure Chemicals Data Compilation. Washington, D.C.: Taylor and Francis, 1989.
MS-Links

Microorganisms emitting the compound
KingdomSpeciesBiological FunctionOrigin/HabitatReference
FungiAntrodia Cinnamomea ATCC 200183nanaLu et al., 2014
BacteriaCollimonas Fungivorans Ter331n/aGarbeva et al., 2013
BacteriaCollimonas Pratensis Ter91n/aGarbeva et al., 2013
BacteriaStreptomyces Griseus Subsp. Griseus DSM 40236nasoilWilkins, 1996
FungiPenicillium Commune Pittnain dry-cured meat products, cheeseSunesson et al., 1995
BacteriaCollimonas Pratensis TER91narhizosphere of Marram grass in sandy dune soils, NetherlandsGarbeva et al., 2014
BacteriaPaenibacillus Sp. P4narhizosphere of Marram grass in sandy dune soils, NetherlandsGarbeva et al., 2014
BacteriaPedobacter Sp. V48narhizosphere of Marram grass in sandy dune soils, NetherlandsGarbeva et al., 2014
BacteriaSerratia Plymuthica PRI-2Cnamaize rhizosphere, NetherlandsGarbeva et al., 2014
BacteriaStreptococcus Mutans DSM 20523 as a biomarker for a breath test for detection of cariesHertel et al., 2015
BacteriaStreptomyces Griseusn/aSchulz and Dickschat, 2007
FungiAmanita OvoideaFranceBreheret et al. 1997
FungiGomphidius GlutinosusFranceBreheret et al. 1997
FungiMycena PuraFranceBreheret et al. 1997
FungiSuillus LuteusFranceBreheret et al. 1997
FungiTricholoma CaligatumFranceBreheret et al. 1997
Method
KingdomSpeciesGrowth MediumApplied MethodVerification
FungiAntrodia Cinnamomea ATCC 200183PDAGC/MSYes
BacteriaCollimonas Fungivorans Ter331sand supplemented with artificial root exudatesHeadspace trapping/GC-MS
BacteriaCollimonas Pratensis Ter91sand supplemented with artificial root exudatesHeadspace trapping/GC-MS
BacteriaStreptomyces Griseus Subsp. Griseus DSM 40236Nutrient agar CM3GC/MS
FungiPenicillium Commune PittDG18GC/MS
BacteriaCollimonas Pratensis TER91sand containing artificial root exudatesGC/MSNo
BacteriaPaenibacillus Sp. P4sand containing artificial root exudatesGC/MSNo
BacteriaPedobacter Sp. V48sand containing artificial root exudatesGC/MSNo
BacteriaSerratia Plymuthica PRI-2Csand containing artificial root exudatesGC/MSNo
BacteriaStreptococcus Mutans DSM 20523Brain-Heart-Infusion agarTenaxâ„¢-trap/GC-MS
BacteriaStreptomyces Griseusn/an/a
FungiAmanita Ovoideaforest soilsolvent extraction, headspace, GCMSno
FungiGomphidius Glutinosusforest soilsolvent extraction, headspace, GCMSno
FungiMycena Puraforest soilsolvent extraction, headspace, GCMSno
FungiSuillus Luteusforest soilsolvent extraction, headspace, GCMSno
FungiTricholoma Caligatumforest soilsolvent extraction, headspace, GCMSno