Results for:
chemical Classification: Chlorides

Chloromethane

Mass-Spectra

Compound Details

Synonymous names
Chloromethylated stryene/divinylbenzene copolymer
Chloromethylated divinylbenzene cross-linked polystyrene
Chloromethylated polystyrene
Chloromethylated styrene-divinylbenzene resin
Monochloromethane
Polystyrene crosslinked with divinylbenzene, chloromethylated
Methylchloride
Chlorocarbon
Chloromethane
Chloromethane solution
Chloromethyne radical
Methylchlorid
Clorometano
NEHMKBQYUWJMIP-UHFFFAOYSA-N
(Chloromethyl)polystyrene
Merrifield inverted exclamation markas peptide resin
METHYL CHLORIDE
methyl-chloride
Artic
Chloor-methaan
MeCl
Metylu chlorek
Chlor-methan
Copolymer of styrene and divinylbenzene, chloromethylated
CH3Cl
Chloromethane on Rasta Resin
Chlorure de methyle
JandaJel™-Cl
AC1O5DVN
Cloruro di metile
Merrifield inverted exclamation mark s peptide resin
Refrigerant R40
StratoSpheres™ PL-CMS resin
Clorometano [Italian]
Methylchlorid [German]
AC1L1MA6
Poly(styrene-co-vinylbenzyl chloride-co-divinylbenzene)
Freon 40
Methane, chloro-
Chloor-methaan [Dutch]
Metylu chlorek [Polish]
UN1063
Chlor-methan [German]
CTK2H7703
HSDB 883
R 40
R-40
CHEMBL117545
Chlorure de methyle [French]
Cloruro di metile [Italian]
A6R43525YO
C19446
CCRIS 1124
Chloromethane, >=99.5%
RCRA waste number U045
DTXSID0021541
LS-1633
OR000106
OR336863
UN 1063
CHEBI:36014
UNII-A6R43525YO
Caswell No. 557
Chloromethane 1.0 M in diethyl ether
MFCD00000872
AI3-01707
LT02467777
Chloromethane 1M, in tert-butyl methyl ether, anhydrous
EPA Pesticide Chemical Code 053202
RCRA waste no. U045
FT-0628715
Methyl chloride, or Refrigerant gas R 40
74-87-3
Chloromethane solution, 1.0 M in diethyl ether
Chloromethane solution, 200 mug/mL in methanol, analytical standard
InChI=1/CH3Cl/c1-2/h1H
Merrifield's peptide resin, 50-100 mesh
2108-20-5
Merrifield's peptide resin, 200-400 mesh
EINECS 200-817-4
Chloromethane on Rasta Resin, 50-100 mesh
Chloromethane solution, 1.0 M in tert-butyl methyl ether, anhydrous
MolPort-001-759-971
(Chloromethyl)polystyrene, extent of labeling: ~1.1 mmol/g Cl loading
(Chloromethyl)polystyrene, extent of labeling: ~1.7 mmol/g Cl loading
(Chloromethyl)polystyrene, porous, extent of labeling: ~5.5 mmol/g Cl loading
Methyl chloride, or Refrigerant gas R 40 [UN1063] [Flammable gas]
Methyl chloride, or Refrigerant gas R 40 [UN1063] [Flammable gas]
StratoSpheres(TM) PL-CMS resin, 30-40 mesh, extent of labeling: 1.0 mmol/g loading, 1 % cross-linked
StratoSpheres(TM) PL-CMS resin, 30-40 mesh, extent of labeling: 2.0 mmol/g loading, 1 % cross-linked
StratoSpheres(TM) PL-CMS resin, 50-100 mesh, extent of labeling: 2.0 mmol/g loading, 1 % cross-linked
StratoSpheres(TM) PL-CMS resin, 50-100 mesh, extent of labeling: 4.0 mmol/g loading, 1 % cross-linked
StratoSpheres(TM) PL-CMS resin, 100-200 mesh, extent of labeling: 1.0 mmol/g loading, 1 % cross-linked
StratoSpheres(TM) PL-CMS resin, 100-200 mesh, extent of labeling: 2.0 mmol/g loading, 1 % cross-linked
StratoSpheres(TM) PL-CMS resin, 200-400 mesh, extent of labeling: 1.0 mmol/g loading, 1 % cross-linked
Merrifield's peptide resin, 70-90 mesh, extent of labeling: 1.0-1.5 mmol/g Cl- loading, 1 % cross-linked
Merrifield's peptide resin, 70-90 mesh, extent of labeling: 1.5-2.0 mmol/g Cl- loading, 1 % cross-linked
Merrifield's peptide resin, 50-100 mesh, extent of labeling: 2.5-4.0 mmol/g Cl- loading, 1 % cross-linked with divinylbenzene
Merrifield's peptide resin, 100-200 mesh, extent of labeling: 3.5-4.5 mmol/g Cl- loading, 1 % cross-linked
Merrifield's peptide resin, 200-400 mesh, extent of labeling: 1.0-1.5 mmol/g Cl- loading, 2 % cross-linked
Merrifield's peptide resin, 200-400 mesh, extent of labeling: 1.5-2.0 mmol/g Cl- loading, 1 % cross-linked
Merrifield's peptide resin, 200-400 mesh, extent of labeling: 2.0-2.5 mmol/g Cl- loading, 2 % cross-linked
Merrifield's peptide resin, 200-400 mesh, extent of labeling: 3.0-3.5 mmol/g Cl- loading, 1 % cross-linked
Merrifield's peptide resin, 200-400 mesh, extent of labeling: 3.5-4.5 mmol/g Cl- loading, 1 % cross-linked
JandaJel(TM)-Cl, 100-200 mesh, extent of labeling: 0.8-1.2 mmol/g Cl loading, 2 % cross-linked
JandaJel(TM)-Cl, 50-100 mesh, extent of labeling: 0.45-0.70 mmol/g Cl loading, 2 % cross-linked
JandaJel(TM)-Cl, 200-400 mesh, extent of labeling: 0.45-0.70 mmol/g Cl loading, 2 % cross-linked
Microorganism:

Yes

IUPAC namechloromethane
SMILESCCl
InchiInChI=1S/CH3Cl/c1-2/h1H3
FormulaCH3Cl
PubChem ID6327
Molweight50.49
LogP0.84
Atoms5
Bonds4
H-bond Acceptor0
H-bond Donor0
Chemical ClassificationChlorides halogenated compounds

mVOC Specific Details

Volatilization
The Henry's Law constant for methyl chloride is 8.82X10-3 atm-cu m/mole(1). This Henry's Law constant indicates that methyl chloride is expected to volatilize rapidly from water surfaces(2). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(2) is estimated as 2.1 hours(SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(2) is estimated as 2.8 days(SRC). Methyl chloride's Henry's Law constant indicates that volatilization from moist soil surfaces may occur(SRC). Methyl chloride is expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 4,300 mm Hg at 25 deg C(3).
Literature: (1) Gossett JM; Environ Sci Technol 21: 202-8 (1987) (2) Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 15-1 to 15-29 (1990) (3) Daubert TE, Danner RP; Physical and thermodynamic properties of pure chemicals: data compilation. Design Inst Phys Prop Data, Amer Inst Chem Eng. NY,NY: Hemisphere Pub. Corp 4 Vol (1989)
Literature: #The volatilization half-life for 1 ppm methyl chloride from a stirred beaker 6.5 cm deep is 27.6 min(1) which converts to a half-life at a 1 m depth of 7.1 hr(SRC). According to a mathematical model, the cumulative volatilization loss of methyl chloride during the first year after placement 1 m beneath the ground, assuming no water evaporation, is 66.9% and 22.3% for sandy and clay soil, respectively(2). When the buried methyl chloride is subject to 0.1 cm/day of steady upward water flow (water evaporation) the cumulative loss at the end of a year is 77.0% for sandy soil and 42.7% for clay soil(SRC).
Literature: (1) Dilling WL; Environ Sci Technol (1977) (2) Jury WA et al; Water Resources Res 26: 13-20 (1990)
Soil Adsorption
Using a structure estimation method based on molecular connectivity indices(1), the Koc for methyl chloride can be estimated to be 13(SRC). According to a classification scheme(2), this estimated Koc value suggests that methyl chloride is expected to have very high mobility in soil.
Literature: (1) US EPA; Estimation Program Interface (EPI) Suite. Ver. 4.11. Nov, 2012. Available from, as of Jan 19, 2016: http://www2.epa.gov/tsca-screening-tools (2) Swann RL et al; Res Rev 85: 17-28 (1983)
Vapor Pressure
PressureReference
4300 mm Hg at 25 deg CDaubert, T.E., R.P. Danner. Physical and Thermodynamic Properties of Pure Chemicals Data Compilation. Washington, D.C.: Taylor and Francis, 1989.

Microorganisms emitting the compound
KingdomSpeciesBiological FunctionOrigin/HabitatReference
BacteriaBacillus Subtilis GB03n/aLee et al., 2012
FungiFomes Sp.n/aStotzky and Schenk, 1976
Method
KingdomSpeciesGrowth MediumApplied MethodVerification
BacteriaBacillus Subtilis GB03Tryptic soy agarSPME coupled with GC-MS
FungiFomes Sp.n/an/a