Results for:
PubChem ID: 8254

Methoxymethane

Mass-Spectra

Compound Details

Synonymous names
DIMETHYL ETHER
Methoxymethane
Methyl ether
Dimethyl oxide
115-10-6
Oxybismethane
Methane, oxybis-
Methyl oxide
Wood ether
Dymel A
Ether, dimethyl
Ether, methyl
Demeon D
Methane, 1,1'-oxybis-
(CH3)2O
HSDB 354
UNII-AM13FS69BX
EINECS 204-065-8
AM13FS69BX
CH3-O-CH3
CHEBI:28887
157621-61-9
1,1'-OXYBISMETHANE
DTXSID8026937
EC 204-065-8
DIMETHYL ETHER (MART.)
DIMETHYL ETHER [MART.]
methylether
N,N-Dimethyl ether
Dimethyl ether, puriss., >=99.9% (GC)
UN1033
monomethylether
Dimehtylether
methoxy methane
Dymel
monomethyl ether
oxybis(methane)
mono methyl ether
Dimethyl ether 99%
OMe2
Dimethyl ether, >=99%
DIMETHYL ETHER [MI]
DIMETHYL ETHER [HSDB]
DIMETHYL ETHER [INCI]
Dimethyl ether, >=99.9%
DIMETHYL ETHER [VANDF]
CHEMBL119178
DTXCID106937
DIMETHYL ETHER [WHO-DD]
DTXSID80167862
MFCD00008494
AKOS015915866
Dimethyl ether, puriss., >=99.8%
UN 1033
InChI=1/C2H6O/c1-3-2/h1-2H
Dimethyl ether [UN1033] [Flammable gas]
M0224
NS00002398
Q408050
2F2
Microorganism:

Yes

IUPAC namemethoxymethane
SMILESCOC
InchiInChI=1S/C2H6O/c1-3-2/h1-2H3
FormulaC2H6O
PubChem ID8254
Molweight46.07
LogP0.1
Atoms3
Bonds0
H-bond Acceptor1
H-bond Donor0
Chemical Classificationethers
CHEBI-ID28887
Supernatural-IDSN0201589

mVOC Specific Details

Boiling Point
DegreeReference
24.82 °C peer reviewed
Volatilization
The Henry's Law constant for dimethyl ether is estimated as 5.9X10-3 atm-cu m/mole(SRC) from its vapor pressure, 4450 mm Hg(1), and water solubility, 4.6X10+4 mg/l(2). This Henry's Law constant indicates that dimethyl ether is expected to volatilize rapidly from water surfaces(3). Based on this Henry's Law constant, the estimated volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(3) is approximately 2.4 hours(SRC). The estimated volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(3) is approximately 2.8 days(SRC). Dimethyl ether's Henry's Law constant(1,2) indicates that volatilization from moist soil surfaces may occur(SRC). Volatilization of dimethyl ether from dry soil surfaces is expected(SRC) based upon this compound's vapor pressure(1).
Literature: (1) Riddick JA et al; Organic Solvents: Physical Properties and Methods of Purification. Techniques of Chemistry. 4th ed. NY, NY: Wiley-Interscience (1986) (2) Hine J, Mookerjee PK; J Org Chem 40: 292-8 (1975) (3)Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 15-1 to 15-29 (1990)
Soil Adsorption
The Koc of dimethyl ether is estimated as approximately 27(SRC), using a log Kow of 0.10(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that dimethyl ether is expected to have very high mobility in soil(SRC).
Literature: (1) Hansch C et al; Exploring QSAR. Hydrophobic, Electronic, and Steric Constants. ACS Prof Ref Book. Heller SR (consult ed) Washington, DC: Amer Chem Soc p. 5 (1995) (2) Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 4-9 (1990) (3) Swann RL et al; Res Rev 85: 23 (1983)
Vapor Pressure
PressureReference
4450 mm Hg at 25 deg CRiddick, J.A., W.B. Bunger, Sakano T.K. Techniques of Chemistry 4th ed., Volume II. Organic Solvents. New York, NY: John Wiley and Sons., 1985., p. 1325
Massbank-Links

Species emitting the compound
KingdomSpeciesBiological FunctionOrigin/HabitatReference
EukaryotaXylaria Sp.naHaematoxylon brasiletto, Morelos, MexicoSánchez-Ortiz et al. 2016
ProkaryotaAchromobacter Sp.the results led us to propose a possible new direct long-distance mechanism of action for WT antagonistic F. oxysporum that is mediated by vocsNAMinerdi et al. 2009
EukaryotaSaccharomyces CerevisiaeNANAHarris et al. 2021
Meyerozyma GuilliermondiiXiong et al. 2023
Method
KingdomSpeciesGrowth MediumApplied MethodVerification
EukaryotaXylaria Sp.PDA mediumSPME-GC/MSyes
ProkaryotaAchromobacter Sp.LB mediumSPME/GC-MS no
EukaryotaSaccharomyces Cerevisiaemalt extract brothHS-SPME with GC-MSno
Meyerozyma GuilliermondiiYEPD, 10 g/L yeast extrac, 20 g/L peptone, 20 g dextroseGC-MS and GC-IMSno