N-METHYLANILINE

100-61-8

Methylaniline

Monomethylaniline

Benzenamine, N-methyl-

N-Methyl aniline

Methylphenylamine

N-Methylbenzenamine

N-Monomethylaniline

N-Phenylmethylamine

N-Methylaminobenzene

(Methylamino)benzene

Aniline, N-methyl-

Anilinomethane

N-Methylphenylamine

Benzeneamine, N-methyl-

methyl-phenyl-amine

NSC 3502

N-Methyl-N-phenylamine

TH45GK410O

DTXSID9021841

CHEBI:15733

NSC-3502

CCRIS 2870

HSDB 1654

EINECS 202-870-9

UN2294

UNII-TH45GK410O

N-metylaniline

N-Methlaniline

AI3-19498

N-Methylanlne

N-methyl-aniline

methyl(phenyl)amine

methyl-phenyl amine

n-methylphenyl amine

N-methyl phenylamine

N-methyl-benzenamine

MFCD00008283

N-Methylanilinium ion

N-methyl-phenyl-amine

ANILINE,N-METHYL

N-Methylaniline, 98%

METHYLANILINE [MI]

N-Methyl-N-phenylamine #

EC 202-870-9

N-Methylaniline, >=99%

SCHEMBL4454

WLN: 1MR

MLS002415757

BIDD:ER0250

BIDD:GT0230

CHEMBL170781

DTXCID301841

SCHEMBL1415355

NSC3502

HMS3039I05

N-Methylaniline, analytical standard

Tox21_200298

STL183283

AKOS000119086

AM10675

MCULE-6046773954

RP10006

UN 2294

N-Methylaniline [UN2294] [Poison]

NCGC00091265-01

NCGC00091265-02

NCGC00257852-01

AS-12865

BP-31133

CAS-100-61-8

SMR001370917

N-Methylaniline, purum, >=98.0% (GC)

M0147

NS00010869

EN300-19055

C02299

J-000182

J-523671

Q1959597

F2190-0405

Z104472478

InChI=1/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H

1MR

The Henry's Law constant for N-methylaniline estimated from its vapor pressure, 0.453 mm Hg(1), and water solubility, 5624 mg/L(2), is 1.14X10-5 atm-cu-m/mol(SRC). Using this value for the Henry's Law constant, one can estimate a volatilization half-life of 3.5 days for N-methylaniline in a model river 1 m deep flowing at 1 m/s with a wind speed of 3 m/s(3). Similarly, the volatilization half-life for N-methylaniline from a model lake 1 m deep, with a 0.05 m/s current and a 0.5 m/s wind is estimated to be 28 days(3).
Literature: (1) Riddick JA et al; Organic Solvents 4th ed; NY, NY: Wiley (1986) (2) Yalkowsky SH, Dannenfelser RM; Aquasol Data Base of Water Solubility Ver 5, Tuscon,. AZ: Univ Arizona, College of Pharmacy (1992) (3) Lyman WJ et al; Handbook of Chemical Property Estimation Methods, NY: McGraw-Hill Chapt 15 (1982)

Since the pKa of N-methylaniline is 4.848(2), N-methylaniline will be partially ionized at acidic environmental pHs and its adsorption to soil would be expected to be pH-dependent(SRC). The Koc for N-methylaniline predicted from molecular structure is 65(3). According to a suggested classification scheme(5), this estimated Koc suggests that N- methylaniline will be highly mobile in soil(SRC). Batch equilibrium studies used to determine the adsorption isotherms for N-methylaniline to a Podzol (4.85% OC pH 2.8), an Alfisol (1.25% OC, pH 6.7) and a sediment (1.58% OC, pH 7.1) yielded the results (soil, Freundlich adsorption constants (Kf), Freundlich exponent (1/n), Koc): Podzol, 22.29, 0.89, 460; Alfisol, 0.59, 0.78, 47; Sediment, 1.12, 0.77, 71(1). N-Methylaniline will be almost completely ionized at the pH of the Podzol and therefore ionic interactions may be dominant(1,SRC). N-Methylaniline reacts slowly with humates possibly by adding to quinoidal structures in the humic substances(4). Covalent bond formation is inferred by the lack of extractability of the aniline from the humic material as well as reactions with model compounds(4).
Literature: (1) Von Oepen B et al; Chemosphere 22: 285-304 (1991) (2) Riddick JA et al; Organic Solvents 4th ed; NY, NY: Wiley (1986) (3) Meylan WM et al; Environ Sci Technol 26:1560-7 (1992) (4) Parris GE; Environ Sci Technol 14: 1099-105 (1980) (5) Swann RL et al; Res Rev 85:17-28 (1983)