Results for:
PubChem ID: 6616

2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptane

Mass-Spectra

Compound Details

Synonymous names
CAMPHENE
79-92-5
Comphene
2,2-Dimethyl-3-methylenenorbornane
(+/-)-Camphene
DL-Camphene
3,3-Dimethyl-2-methylenenorbornane
3,3-Dimethyl-2-methylenenorcamphane
2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptane
FEMA No. 2229
2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
565-00-4
Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-
CCRIS 3783
HSDB 900
NSC 4165
3,3-Dimethyl-2-methylenenorcamphene
EINECS 201-234-8
EINECS 209-275-3
UNII-G3VG94Z26E
CHEBI:3830
G3VG94Z26E
DTXSID8026488
AI3-01775
CAMPHENE, DL-
NSC-4165
2,2-Dimethyl-3-methylenebicyclo(2.2.1)heptane
Camphene (2,2-dimethyl-3-methylene-norbornane)
Bicyclo(2.2.1)heptane, 2,2-dimethyl-3-methylene-
DTXCID006488
CAMPHENE, (+/-)-
Camphene, (1R,4S)-(+)-
EC 201-234-8
(1)-2,2-Dimethyl-3-methylenebicyclo(2.2.1)heptane
CAMPHENE (MART.)
CAMPHENE [MART.]
Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1R)-
CAS-79-92-5
2,2-dimethyl-3-methylidenebicyclo(2.2.1)heptane
MFCD00066603
2,2-dimethyl-3-methylene-norbornane
CAMPHENE [FHFI]
CAMPHENE [HSDB]
CAMPHENE [INCI]
CAMPHENE [FCC]
CAMPHENE [MI]
2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane #
CAMPHENE, D,L-
3,3-Dimethylenenorcamphene
CAMPHENE [WHO-DD]
Bicyclo-(2.2.1)heptane
2,2-Dimethyl-3-methylene-
3,3-dimethyl-2-methylidenebicyclo[2.2.1]heptane
CHEMBL2268550
2,2-Dimethyl-3-methylenebicyclo
NSC4165
2,2-Dimethyl-3-methylene-norborane
Tox21_202014
Tox21_303152
BBL033861
STK801857
AKOS004119935
CCG-266137
MCULE-1011863584
NCGC00249149-01
NCGC00257126-01
NCGC00259563-01
WLN: L55 A CYTJ CU1 D1 D1
VS-12317
2,2-DIMETHYL-3-METHYLENE NORBORANE
DB-053130
DB-056393
DB-057848
NS00006622
3,3-DIMETHYL-2-METHYLENE NORCAMPHANE
EN300-20391
(1R,4S)-2,2-dimethyl-3-methylene-norbornane
C06076
E87135
Bicyclo[2.2.1]heptane,2-dimethyl-3-methylene-
Q416775
SR-01000944833
Bicyclo(2.2.1)heptane, 2,2-dimethyl-3-methylene
SR-01000944833-1
CAMPHENE(2,2-DIMETHYL-3-METHYLENE-NORBORNANE)
Z104478010
Microorganism:

Yes

IUPAC name2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptane
SMILESCC1(C2CCC(C2)C1=C)C
InchiInChI=1S/C10H16/c1-7-8-4-5-9(6-8)10(7,2)3/h8-9H,1,4-6H2,2-3H3
FormulaC10H16
PubChem ID6616
Molweight136.23
LogP3.3
Atoms10
Bonds0
H-bond Acceptor0
H-bond Donor0
Chemical Classificationterpenes
CHEBI-ID3830
Supernatural-IDSN0053728

mVOC Specific Details

Boiling Point
DegreeReference
161 °C peer reviewed
Volatilization
The Henry's Law constant for camphene is estimated as 0.098 atm-cu m/mole(SRC) derived from its vapor pressure, 2.5 mm Hg(1), and water solubility, 4.6 mg/L(2). This Henry's Law constant indicates that camphene is expected to volatilize rapidly from water surfaces(3). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(3) is estimated as 1 hour(SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(3) is estimated as 5 days(SRC). Camphene's estimated Henry's Law constant indicates that volatilization from moist soil surfaces may occur(SRC). The potential for volatilization of camphene from dry soil surfaces may exist(SRC) based upon a vapor pressure of 2.5 mm Hg(1).
Literature: (1) Daubert TE, Danner RP; Physical and Thermodynamic Properties of Pure Chemicals Data Compilation. Washington, DC: Taylor and Francis (1989) (2) Chemicals Inspection and Testing Institute; Biodegradation and Bioaccumulation Data of Existing Chemicals Based on the CSCL Japan. Japan Chemical Industry Ecology - Toxicology and Information Center. ISBN 4-89074-101-1 p.4-40 (1992) (3) Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 15-1 to 15-29 (1990)
Soil Adsorption
Using a structure estimation method based on molecular connectivity indices(1), the Koc of camphene can be estimated to be 1000(SRC). According to a classification scheme(2), this estimated Koc value suggests that camphene is expected to have low mobility in soil.
Literature: (1) US EPA; Estimation Program Interface (EPI) Suite. Ver. 4.1. Nov, 2012. Available from, as of May 29, 2015: http://www.epa.gov/oppt/exposure/pubs/episuitedl.htm (2) Swann RL et al; Res Rev 85: 17-28 (1983)
Vapor Pressure
PressureReference
2.5 mm Hg at 25 deg CDaubert, T.E., R.P. Danner. Physical and Thermodynamic Properties of Pure Chemicals Data Compilation. Washington, D.C.: Taylor and Francis, 1989.
MS-Links
1D-NMR-Links
Massbank-Links

Species emitting the compound
KingdomSpeciesBiological FunctionOrigin/HabitatReference
EukaryotaAspergillus FumigatusNANAHeddergott et al. 2014
EukaryotaAspergillus FumigatusNANAAhmed et al. 2018
EukaryotaAmanita OvoideaFranceBreheret et al. 1997
EukaryotaBoletus AestivalisFranceBreheret et al. 1997
EukaryotaCantharellus CibariusFranceBreheret et al. 1997
EukaryotaCystoderma CarchariasFranceBreheret et al. 1997
EukaryotaGomphidius GlutinosusFranceBreheret et al. 1997
EukaryotaHydnum RepandumFranceBreheret et al. 1997
EukaryotaMycena PuraFranceBreheret et al. 1997
EukaryotaMycena RoseaFranceBreheret et al. 1997
EukaryotaSuillus LuteusFranceBreheret et al. 1997
EukaryotaTricholoma SulphureumFranceBreheret et al. 1997
EukaryotaTuber Magnatumn/aItalian geographical areas (Emilia Romagna, Border region area between Emilia Romagna and Marche)Gioacchini et al. 2008
EukaryotaAspergillus Fumigatuscompost Fischer et al. 1999
ProkaryotaPedobacter Sp.narhizosphere of Marram grass in sandy dune soils, NetherlandsGarbeva et al. 2014
EukaryotaPenicillium Communenain dry-cured meat products, cheeseSunesson et al. 1995
EukaryotaSpongiporus Leucomallellusnasaprophytic mostly on wet, old pinesCampos Ziegenbein et al. 2006
EukaryotaFomitopsis PinicolanaGermanyRösecke et al. 2000
EukaryotaAntrodia CinnamomeananaLu et al. 2014
EukaryotaFusarium Culmorumaffects swarming and swimming motility of Serratia plymuthica PRI-2C; affects swarming ability of Collimonas pratensis Ter291sandy dune soil, NetherlandsSchmidt et al. 2015
EukaryotaSaccharomyces CerevisiaeNANALjunggren et al. 2019
EukaryotaSaccharomyces CerevisiaeNANAHarris et al. 2021
Kluyveromyces MarxianusJi et al. 2024
Saccharomyces CerevisiaeJi et al. 2024
Method
KingdomSpeciesGrowth MediumApplied MethodVerification
EukaryotaAspergillus FumigatusBrianSPME/GC-MSno
EukaryotaAspergillus FumigatusAMMTD/GC-MSno
EukaryotaAmanita Ovoideaforest soilsolvent extraction, headspace, GCMSno
EukaryotaBoletus Aestivalisforest soilsolvent extraction, headspace, GCMSno
EukaryotaCantharellus Cibariusforest soilsolvent extraction, headspace, GCMSno
EukaryotaCystoderma Carchariasforest soilsolvent extraction, headspace, GCMSno
EukaryotaGomphidius Glutinosusforest soilsolvent extraction, headspace, GCMSno
EukaryotaHydnum Repandumforest soilsolvent extraction, headspace, GCMSno
EukaryotaMycena Puraforest soilsolvent extraction, headspace, GCMSno
EukaryotaMycena Roseaforest soilsolvent extraction, headspace, GCMSno
EukaryotaSuillus Luteusforest soilsolvent extraction, headspace, GCMSno
EukaryotaTricholoma Sulphureumforest soilsolvent extraction, headspace, GCMSno
EukaryotaTuber Magnatumn/amicroextraction-gas chromatography-mass spectrometry analysis (SPME-GC-MS)no
EukaryotaAspergillus Fumigatusyest extract sucroseTenax/GC-MSno
ProkaryotaPedobacter Sp.sand containing artificial root exudatesGC/MSno
EukaryotaPenicillium CommuneDG18GC/MSno
EukaryotaSpongiporus LeucomallellusnaGC/MSno
EukaryotaFomitopsis PinicolanaGC/MSno
EukaryotaAntrodia CinnamomeaPDAGC/MSyes
EukaryotaFusarium Culmorumpotato dextrose agarGC/MS-Q-TOFno
EukaryotaSaccharomyces Cerevisiaeliquid YPD mediumGC-MSno
EukaryotaSaccharomyces Cerevisiaemalt extract brothHS-SPME with GC-MSno
Kluyveromyces MarxianusSauce Meat during StorageSPME–GC–MSno
Saccharomyces CerevisiaeSauce Meat during StorageSPME–GC–MSno