Results for:
PubChem ID: 6061

Methylhydrazine

Compound Details

Synonymous names
METHYLHYDRAZINE
60-34-4
Hydrazine, methyl-
Methyl Hydrazine
Monomethylhydrazine
Methyl-hydrazine
1-Methylhydrazine
Metylohydrazyna
RCRA waste number P068
N-methylhydrazine
2-methylhydrazine
CH3NHNH2
MMH
UWA30B5Z1J
CHEMBL160520
DTXSID4020874
Monomethyl Hydrazine
Methylhydrazine (mono)
Metylohydrazyna [Polish]
20244-39-7
CCRIS 394
HSDB 1172
EINECS 200-471-4
UN1244
RCRA waste no. P068
UNII-UWA30B5Z1J
BRN 0635645
methyldiazane
methl hydrazine
AI3-52240
N-methyhydrazine
N-methyl hydrazine
N-methyl-hydrazine
2-methyl hydrazine
MeNHNH2
Methylhydrazine, 98%
H2NNHCH3
EC 200-471-4
METHYLHYDRAZINE [MI]
METHYLHYDRAZINE [HSDB]
BCP07836
BBL011339
BDBM50049259
STL146429
AKOS005720746
Methylhydrazine [UN1244] [Poison]
UN 1244
BP-11387
BP-30186
Methylhydrazine, purum, >=98.0% (GC)
M0558
NS00002460
InChI=1/CH6N2/c1-3-2/h3H,2H2,1H
A832701
Q417347
HDN
Microorganism:

Yes

IUPAC namemethylhydrazine
SMILESCNN
InchiInChI=1S/CH6N2/c1-3-2/h3H,2H2,1H3
FormulaCH6N2
PubChem ID6061
Molweight46.072
LogP-0.9
Atoms3
Bonds0
H-bond Acceptor2
H-bond Donor2
Chemical Classificationnitrogen compounds hydrazines

mVOC Specific Details

Boiling Point
DegreeReference
87.5 °C peer reviewed
Volatilization
1,2-Dimethylhydrazine is a weak base with a pKa of 7.87(1). This value indicates that methylhydrazine will partially exist as a cation in water and moist soil surfaces and cations do not volatilize. The Henry's Law constant for the free base of methylhydrazine is estimated as 3X10-6 atm-cu m/mole(SRC) from its vapor pressure, 50 mm Hg(2), and water solubility, 1X10+6 mg/L(3). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(4) is estimated as 5 days (SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(4) is estimated as 62 days(SRC). Methylhydrazine's Henry's Law constant indicates that the free base may volatilize from moist soil surfaces(SRC). The potential for volatilization of methylhydrazine from dry soil surfaces may exist(SRC) based on its vapor pressure(2).
Soil Adsorption
Using a structure estimation method based on molecular connectivity indices(1), the Koc for methylhydrazine can be estimated to be 18(SRC). According to a classification scheme(2), this estimated Koc value suggests that methylhydrazine is expected to have very high mobility in soil. The pKa of methylhydrazine is 7.87(3). This pKa value indicates that this compound will partially exist as a cation in moist soils and cations generally adsorb more strongly to organic carbon and clay than the corresponding free base(4).
Vapor Pressure
PressureReference
43.8

Species emitting the compound
KingdomSpeciesBiological FunctionOrigin/HabitatReference
Aspergillus FlavusKate et al. 2023
Pectobacterium CarotovorumKate et al. 2023
Method
KingdomSpeciesGrowth MediumApplied MethodVerification
Aspergillus Flavusinoculated potato samplesGC-MSno
Pectobacterium Carotovoruminoculated potato samplesGC-MSno