Results for:
PubChem ID: 11169

2,2,4,4,6,6,8,8-octamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane

Compound Details

Synonymous names
OCTAMETHYLCYCLOTETRASILOXANE
556-67-2
Cyclotetrasiloxane, octamethyl-
2,2,4,4,6,6,8,8-Octamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane
Oktamethylcyklotetrasiloxan
Cyclic dimethylsiloxane tetramer
NUC silicone VS 7207
Oktamethylzyklotetrasiloxan
DTXSID7027205
CHEBI:25640
CZ227117JE
2,2,4,4,6,6,8,8-octamethyl-1,3,5,7,2,4,6,8-tetroxatetrasilocane
NSC-345674
OMCTS
DTXCID107205
Union carbide 7207
Silicone SF 1173
MFCD00003269
Cyclomethicone 4
CAS-556-67-2
CCRIS 1327
HSDB 6131
Oktamethylcyklotetrasiloxan [Czech]
EINECS 209-136-7
KF 994
NSC 345674
octamethyl cyclotetrasiloxane
SF 1173
UC 7207
VS 7207
BRN 1787074
UNII-CZ227117JE
bmse000765
EC 209-136-7
octamethyl-cyclotetrasiloxane
SCHEMBL18354
BIDD:ER0157
Dimethylsiloxane Cyclic Tetramer
CHEMBL1869229
CYCLOTETRASILOXANE [INCI]
HMMGMWAXVFQUOA-UHFFFAOYSA-
OCTAMETHYCYCLOTETRASILOXANE
Octamethylcyclotetrasiloxane, 98%
CYCLOMETHICONE 4 [USP-RS]
Tox21_201398
Tox21_300547
CO9810
CYCLOTETRASILOXANE, OCTAMETHYL
NSC345674
AKOS008901191
MCULE-2162943570
OCTAMETHYLCYCLOTETRASILOXANE [MI]
NCGC00164099-01
NCGC00164099-02
NCGC00164099-03
NCGC00254406-01
NCGC00258949-01
OCTAMETHYLCYCLOTETRASILOXANE [HSDB]
CS-0213747
NS00043628
O0142
O9810
F83065
Octamethylcyclotetrasiloxane, analytical standard
Cyclotetrasiloxane, 2,2,4,4,6,6,8,8-octamethyl-
Q2013804
2,2,4,4,6,6,8,8-Octamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane #
Cyclomethicone 4, United States Pharmacopeia (USP) Reference Standard
D4 Cyclomethicone, Pharmaceutical Secondary Standard; Certified Reference Material
d-4
InChI=1/C8H24O4Si4/c1-13(2)9-14(3,4)11-16(7,8)12-15(5,6)10-13/h1-8H3
Microorganism:

Yes

IUPAC name2,2,4,4,6,6,8,8-octamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane
SMILESC[Si]1(O[Si](O[Si](O[Si](O1)(C)C)(C)C)(C)C)C
InchiInChI=1S/C8H24O4Si4/c1-13(2)9-14(3,4)11-16(7,8)12-15(5,6)10-13/h1-8H3
FormulaC8H24O4Si4
PubChem ID11169
Molweight296.61
LogP0
Atoms16
Bonds0
H-bond Acceptor4
H-bond Donor0
Chemical Classificationorganosilicon compounds
CHEBI-ID25640
Supernatural-IDSN0129642

mVOC Specific Details

Boiling Point
DegreeReference
175 °C peer reviewed
Volatilization
The Henry's Law constant for octamethylcyclotetrasiloxane is 13.4 atm-cu m/mole(1). This Henry's Law constant indicates that octamethylcyclotetrasiloxane is expected to volatilize rapidly from water surfaces(2). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(2) is estimated as 5 hours(SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(2) is estimated as 6.8 days(SRC). However, volatilization from water surfaces is expected to be attenuated by adsorption to suspended solids and sediment in the water column. The estimated volatilization half-life from a model pond is 140 days if adsorption is considered(3). Octamethylcyclotetrasiloxane's Henry's Law constant indicates that volatilization from moist soil surfaces may occur(SRC). Octamethylcyclotetrasiloxane is expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 1.05 mm Hg(4). Evaporation of octamethylcyclotetrasiloxane was measured in soil studies and found to occur with rates varying with moisture content, soil type and relative humidity(5). 14C-Labeled octamethylcyclotetrasiloxane was removed from municipal waste by both adsorption to sludge and volatilization(6); the majority of the material was removed via volatilization(6); after 3 days, 49% of the material in the aeration/secondary clarifier was removed by volatilization while only 10% was removed by adsorption to sludge(6).
Soil Adsorption
Adsorption studies using three soils from the United Kingdom (silt loam, sandy loam and sandy clay loam) determined octamethylcyclotetrasiloxane log Koc values of 4.17-4.27 with an average log Koc of 4.22 (Koc of 16600)(1). According to a classification scheme(2), these Koc values suggest that octamethylcyclotetrasiloxane is expected to be immobile in soil.
Massbank-Links

Species emitting the compound
KingdomSpeciesBiological FunctionOrigin/HabitatReference
ProkaryotaStenotrophomonas Maltophiliaantifungal activity against Colletotrichum nymphaeaeisolated from the healthy strawberry leaf in Kamyaran, Kurdistan provinceAlijani et al. 2020
Method
KingdomSpeciesGrowth MediumApplied MethodVerification
ProkaryotaStenotrophomonas MaltophiliaNA mediaGC-MSno