Results for:
PubChem ID: 6348

Methanedithione

Mass-Spectra

Compound Details

Synonymous names
Schwefelkohlenstoff
Carbondisulphide
Koolstofdisulfide
disulfidocarbon
Dithiocarbonic anhydride
Dithioxomethane
Kohlendisulfid
methanedithione
Sulfocarbonic anhydride
Sulphocarbonic anhydride
Carbon bisulfuret
Carbon bisulphide
Carbon disulphide
carbon-disulphide
Dithioxomethane #
Kohlendisulfid (schwefelkohlenstoff)
QGJOPFRUJISHPQ-UHFFFAOYSA-N
Weeviltox
Wegla dwusiarczek
Carbon bisulfide
CARBON DISULFIDE
Carbon sulphide
Koolstofdisulfide (zwavelkoolstof)
Carbon disulfide cation
Carbon-disulphide-
Schwefelkohlenstoff [German]
Solfuro di carbonio
Sulfure de carbone
Sulphuret of carbon
Weevil-Tox
AC1L1MBX
AC1Q7EYQ
Alcohol of sulfur
Carbon disulfide, ACS reagent
Carbon disulfide, CP
Kohlendisulfid (schwefelkohlenstoff) [German]
Wegla dwusiarczek [Polish]
HSDB 52
Koolstofdisulfide (zwavelkoolstof) [Dutch]
KSC377M2H
ACMC-20ali2
UN1131
C1955
Carbon disulfide, spectrophotometric grade, >=99%
Carbone (sulfure de)
Carbone (sulfuro di)
Carbonio (solfuro di)
CTK2H7623
Solfuro di carbonio [Italian]
RP18362
C19033
Carbon disulfide [BSI:ISO]
CCRIS 5570
RCRA waste number P022
S54S8B99E8
300030XA
Carbon disulfide, anhydrous, >=99%
Carbon sulfide (CS2)
CHEMBL1365180
DTXSID6023947
IN002279
LS-1657
OR261913
UN 1131
300030X
CHEBI:23012
DSSTox_CID_3947
NCI-C04591
Sulfure de carbone [ISO-French]
UNII-S54S8B99E8
AN-23840
DSSTox_GSID_23947
Caswell No. 162
DSSTox_RID_77238
AI3-08935
RTR-024207
TR-024207
AKOS009075983
Carbon disulfide solution, 5 M in THF
Carbonio (solfuro di) [Italian]
EPA Pesticide Chemical Code 016401
RCRA waste no. P022
BRN 1098293
Carbone (sulfure de) [French]
FT-0083177
FT-0623475
75-15-0
I14-19641
Tox21_111082
Tox21_201168
Carbon disulfide, ACS reagent, >=99.9%
CAS-75-15-0
Carbon disulfide, for HPLC, >=99.9%
Carbon disulfide, JIS special grade, >=99.0%
NCGC00091108-01
NCGC00091108-02
NCGC00258720-01
Carbon disulfide, SAJ first grade, >=98.0%
EINECS 200-843-6
12539-80-9
Carbon disulfide [UN1131] [Flammable liquid]
Carbon disulfide solution, 5000 mug/mL in methanol, analytical standard
Carbon disulfide solution, certified reference material, 5000 mug/mL in methanol
355120-85-3
Carbon disulfide, ReagentPlus(R), purified by redistillation, >=99.9%
MolPort-001-768-563
Carbon disulfide [UN1131] [Flammable liquid]
Carbon disulfide, p.a., 99.5%
Carbon disulfide, purum, >=99.0% (GC)
Carbon disulfide, ReagentPlus(R), low benzene, >=99.9%
Carbon disulfide, puriss., >=99.5% (GC)
Carbon-12C disulfide, 99.9 atom % 12C
Carbon disulfide, HPLC, 99.8% min. 1L
4-03-00-00395 (Beilstein Handbook Reference)
Carbon disulfide, puriss., low in benzene, >=99.5% (GC)
Carbon disulfide, puriss. p.a., >=99.9% (GC)
Carbon disulfide, for IR spectroscopy, puriss. p.a., ACS reagent, reag. Ph. Eur., >=99.9% (GC)
IUPAC namemethanedithione
SMILESC(=S)=S
InchiInChI=1S/CS2/c2-1-3
FormulaCS2
PubChem ID6348
Molweight76.13
LogP1.95
Atoms3
Bonds2
H-bond Acceptor0
H-bond Donor0
Chemical ClassificationSulfides sulfur compounds

mVOC Specific Details

Volatilization
The Henry's Law constant for carbon disulfide is 1.44X10-2 atm-cu m/mole at 24 deg C(1). This Henry's Law constant indicates that carbon disulfide is expected to volatilize rapidly from water surfaces(2). Based on this Henry's Law constant, the estimated volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec) (2) is approximately 2.6 hours(SRC). The estimated volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec) (2)is approximately 3.5 days(SRC). Carbon disulfide's Henry's Law constant(1) indicates that volatilization from moist soil surfaces is expected to occur(SRC). The potential for volatilization of carbon disulfide from dry soil surfaces may exist(SRC) based upon the vapor pressure of 359 mm Hg(3).
Literature: (1) Elliot S; Atmos Environ 23: 1977-80 (1989) (2) Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington DC: Amer Chem Soc pp. 15-1 to 15-29 (1990) (3) Yaws CL; Handbook of Vapor Pressure, Vol 1, Houston,TX: Gulf Pub Co (1994)
Soil Adsorption
The Koc of carbon disulfide is estimated as approximately 270(SRC), using a log Kow of 1.94(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that carbon disulfide is expected to have moderate mobility in soil(SRC). The avg adsorption of carbon disulfide after 10 minutes by 4 air-dried soils was 46% but only 12% by the same soils at 50% water-holding capacity(4). However, after 8 hr the rate of adsorption was greater by moist soil, but only when the soil was unsterilized(4). Further experiments suggest that this 'adsorption' in moist soils is the result of microbial action(4).
Literature: (1) Hansch C et al; Exploring QSAR. Hydrophobic, Electronic, and Steric Constants. ACS Prof Ref Book. Heller SR (consult ed) Washington,DC: Amer Chem Soc p 3 (1995) (2) Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington,DC: Amer Chem Soc pp. 4-9 (1990) (3) Swann RL et al; Res Rev 85: 23 (1983) (4) Bremner JM, Banwart WL; Soil Biol Biochem 8: 79-83 (1976)
Vapor Pressure
PressureReference
359 mm Hg at 25 deg CYaws CL; Handbook of Vapor Pressure, Vol 1, Houston,TX: Gulf Pub Co. (1994)
MS-Links

Microorganisms emitting the compound
KingdomSpeciesBiological FunctionOrigin/HabitatReference
BacteriaCarnobacterium Divergens 9Pn/aErcolini et al., 2009
BacteriaPseudomonas Fragi 25Pn/aErcolini et al., 2009
BacteriaPseudomonas Putidan/aSchulz and Dickschat, 2007
BacteriaSerratia Proteamaculans 42Mn/aErcolini et al., 2009
FungiOgataea Pininamycangia of Dendroctonus brevicomisDavis et al., 2011
BacteriaPseudomonas Putida KT 2442nanaSchoeller et al., 1997
Method
KingdomSpeciesGrowth MediumApplied MethodVerification
BacteriaCarnobacterium Divergens 9Pn/an/a
BacteriaPseudomonas Fragi 25Pn/an/a
BacteriaPseudomonas Putidan/an/a
BacteriaSerratia Proteamaculans 42Mn/an/a
FungiOgataea PiniMEAGC/MS
BacteriaPseudomonas Putida KT 2442AB medium + 1% citrate or 0,02% citrate or 1% glucose +1% casaminoacid GC-FID,GC/MS